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1 article(s) from Nordmann, Jan

One-pot three-component synthesis and photophysical characteristics of novel triene merocyanines

Christian Muschelknautz,
Robin Visse,
Jan Nordmann and
Thomas J. J. Müller

Beilstein J. Org. Chem. 2014, 10, 599–612, doi:10.3762/bjoc.10.51

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Graphical Abstract

Figure 1: Linear push–pull solid-state diene lumophores with conformationally flexible and fixed acceptor moi...

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Scheme 1: Three-component synthesis of 1-styryleth-2-enylideneindolones 8.

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Figure 2: DFT-computed energy differences of the stereoisomers of 2Z,4Z-8a and 2Z,4E-8a.

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Scheme 2: Three-component synthesis of 4-(1,3,3-trimethylindolin-2-ylidene)but-2-en-1-ylideneindolones 10.

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Figure 3: DFT-computed energy differences of the stereoisomers of 10a and 10h.

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Scheme 3: Mechanistic rationale of the three-component sequence furnishing the 1-styryleth-2-enylideneindolon...

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Figure 4: DFT-computed (B3LYP functional, 6-31G* basis set) HOMO (left) and LUMO (right) of merocyanine 8a.

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Figure 5: Absorption and emission spectrum of the dropcasted film of compound 8a (recorded at room temperatur...

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Figure 6: Absorption spectrum of the dropcasted film of compound 10d (recorded at room temperature, normalize...

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Figure 7: Absorption spectra of compound 10h in dichloromethane (right trace) and of the dropcasted film (lef...

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Figure 8: DFT-computed (B3LYP functional, 6-311G(d,p) basis set) FMOs (HOMO, bottom; LUMO (center), and LUMO+...

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Published 05 Mar 2014

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